For that criteria it's probably - Flawless, National Treasures, Immaculate Collection and Eminence which are all their top shelf high-end.
Then it takes a step down to Noir & Impeccable and maybe Spectra, although Impeccable has no patches.
If buying singles you can pick and choose what you like, if thinking of buying a box you have to be careful as sticker autos have crept into sets within high end releases and rookie stuff is likely to be non-associated or player worn as opposed to game worn.
Plus Panini's time in numbered...